Abstract
AbstractA method for the rearrangement of alkyne-tethered cyclohexadienone to furnish meta-enone-substituted anisoles using arene diazonium tetrafluoroborate salts as precatalyst was developed. The reaction proceeds via intramolecular 1,6-enyne cyclization-aromatization and oxetene ring opening. The same protocol was also employed to obtain phthalide-substituted anisoles. The reactions are atom economic, have a broad substrate scope and amenable to gram-scale synthesis. Further synthetic transformations of the products were also performed.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
