Abstract

Treatment of γ-( tert -butyldimethylsiloxy)- or γ-(trimethylsiloxy)allenes bearing various groups at the ether carbon with N-iodosuccinimide resulted in the formation of iodocyclization products, 1-iodo-1-(tetrahydrofuran-2′-yl)ethenes, in good yields and with high selectivity for the cis diastereomer.

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