Abstract

AbstractThe activity of {Pd[C6H2(CH2CH2NH2)‐(OMe)2,3,4] (µ‐Br)}2 complex was investigated in the Heck–Mizoroki CC cross‐coupling reaction under conventional heating and microwave irradiation conditions in molten salt tetrabutylammonium bromide as the solvent and promoter at 130 °C. This complex in these conditions is an active and efficient catalyst for the Heck reaction of aryl iodides, bromides and even chlorides, and also arenesulfonyl chlorides. Copyright © 2011 John Wiley & Sons, Ltd.

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