Ac Stark splitting in intense stochastic driving fields with Gaussian statistics and non-Lorentzian line shape

Abstract

Lorentzian models for laser line shapes lead to qualitatively incorrect results for off-resonance excitation of atoms. This paper is the first attempt to present a theory of the nonperturbative interaction of an atom with a chaotic field (representing multimode laser radiation having strong amplitude fluctuations) with a line shape falling off faster than a Lorentzian. To this end we suggest a stochastic Markovian model for a non-Lorentzian chaotic field. To solve the multiplicative stochastic differential equations describing the atom-field interaction we propose a marginal characteristic function approach. This not only reproduces our earlier results in a more elegant way and establishes the relationship between approaches used by other authors in a different context, but also provides the simplest possible basis for our present discussion of ac Stark splitting in double optical resonance. While for a chaotic field with a Lorentzian line shape the asymmetry of the two-peaked off-resonance spectrum is reversed for all values of the detuning compared with the monochromatic case, our present model predicts a reversed peak asymmetry only for detunings smaller than a few laser bandwidths in agreement with experiment. The on-resonance spectrum is dominated by the amplitude fluctuations and is only weakly affected by changes of the spectral line shape of the laser.