Ac ionic conductivity of hollandite type compounds from 100 Hz to 37.0 GHz

Abstract

The frequency- and temperature-dependences of a.c. ionic conductivity of one-dimensional super-ionic conductors K-priderites with a hollandite type structures were investigated from 100 Hz to 37.0 GHz. Four kinds of K-priderite, K 1.6Mg 0.8Ti 7.2O 16, (K 1.3, Li 0.1) Mg 0.7Ti 7.3O 16, K 1.6Al 1.6Ti 6.4O 16 and (K 1.3, Li 0.2) Al 1.5Ti 6.5O 16, were studied. An equivalent circuit to combine the data of the complex conductivity at low and high frequencies was proposed. The data of complex conductivity at low frequencies can be analyzed in terms of the moving box model proposed by Beyeler et al. The transport of K + ions at low frequencies is characterized by the cooperative motion of the K + ions with various mobilities and is accompanied with the polarization of the K + ions in the channels. The ion transport across intrinsic barriers at or above microwave frequencies is characterized by the frequency-independent ionic conductivity and is interpreted by the configurational model proposed by Beyeler et al. The height of intrinsic barriers is related to the lattice constants of a crystal.