Abundance and Speciation of Surface Oxygen on Nanosized Platinum Catalysts and Effect on Catalytic Activity

Abstract

Oxygen at the surface of nanosized platinum has a direct effect on catalytic activity of oxidation–reduction chemical reactions. However, the abundance and speciation of oxygen remain uncertain for platinum with different particle size and shape characteristics, which has hindered the development of fundamental property–activity relationships. We have characterized two commercially available platinum nanocatalysts known as Pt black and Pt nanopowder to evaluate the effects of synthesis and heating conditions on the physical and surface chemical properties, as well as on catalytic activity. Characterization using complementary electron microscopy, X-ray scattering, and spectroscopic methods showed that the larger average crystallite size of Pt nanopowder (23 nm) compared to Pt black (11 nm) corresponds with a 70% greater surface oxygen concentration. Heating the samples in air resulted in an increase in surface oxygen concentration for both nanocatalysts. Surface oxygen associated with platinum is in the f...