Abstract

The absorption spectrum of naphthalene has been studied in rare-gas matrices (RGM). Molar extinction coefficients have been determined and oscillator strengths of various π ∗-π transitions deduced. Bands in the 6.5 to 7.1 eV region, some of which were previously observed and interpreted as members of an impurity exciton (Rydberg) series, have been assigned to a π ∗-π transition. The results are compared with the theoretical prediction.

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