Absorption of NO laser-induced fluorescence by hot O 2 and CO 2

Abstract

Compared to conventional combustion in gasoline engines, Gasoline Controlled Auto-Ignition (GCAI) has the potential to significantly reduce both fuel consumption and nitrogen oxides (NOX) raw emissions. However, GCAI combustion still has a limited operating range due to limitations in combustion stability at low loads and high rates of cylinder pressure rise at high engine loads. Previous research identified hydrogen peroxide (H2O2) decomposition as an effective means to control GCAI, which is formed among other species with pilot fuel injection during the negative valve overlap (NVO) phase. Since the chemical effect of H2O2 on the main combustion has not been experimentally confirmed so far, the aim of the experimental study described in this paper is to detect H2O2 during early compression using optical methods. This is approached by conducting Photofragmentation Laser-Induced Fluorescence (PFLIF) of H2O2 by a pump laser and simultaneous hydroxyl radical Laser-Induced Fluorescence (OH-LIF) detection in the combustion chamber of a dedicated GCAI single-cylinder research engine at low loads after NVO with pilot injection (PI). Thereto, the pilot injection strategy as well as the global air/fuel ratio (AFR) are varied. Interestingly, no H2O2, hydroxyl (OH) or hydroperoxyl (HO2) constituents were detected under the operating conditions studied, despite relatively high pilot injection fuel masses and a highly accurate H2O2 detection limit of about 1 ppm. Numerical three-dimensional computational fluid dynamics (3D-CFD) combustion simulations using a semi-detailed reaction kinetic mechanism predicted 5–8 times higher H2O2 concentrations than the detection limit, yielding an uncertainty estimate of the numerical methods. Furthermore, the 3D-CFD simulations showed a significant mixture stratification which is a possible reason for the lack of H2O2 detection under these operating conditions.