Abstract

Tl containing Ar, Kr, and Xe matrices were produced by electrode sputtering in a self-igniting pulsed-discharge unit. The absorption and laser-induced fluorescence spectra of the thallium atoms have been investigated. The results are compared with our recent observations of gas phase diatomic thallium–rare gas (Tl–Rg) clusters. The observed linewidths, shifts, and relaxation dynamics are qualitatively interpreted on the basis of the pairwise Tl–Rg interaction potentials.

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