Abstract

The absolute rotationless transition moment squared for the X1Σ+v=3←v=0 band of CO is measured to be |R3–0|2=1.713 (−20, +33)×10−7 Debye2. This value is about 8.6% smaller than the value assumed for HITRAN 2000. The measured Herman–Wallis intensity factor of this band is F=1+0.01168(11)m+0.0001065(79)m2. The determination of self-broadening coefficients is improved with the inclusion of line narrowing; self-shifts are also reported.

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