Abstract
AbstractThe absolute Raman intensities of the fundamental bands of vapour HCCl3Jand DCCl3 have been measured with an experimental accuracy of ten per cent. The vibrational potential function for chloroform has been calculated by a standard least squares forceconstant refinement including data on anharmonicity corrected values of the 12C/13C displacements and also the absolute intensities measured in this work. The results are compared with those of Previous works and the influence of the intensity data upon the refinement is discussed.
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