Abstract

Water lines in the infrared are convenient frequency references. We present absolute positions of several H216O ro-vibrational transitions around 790 nm using comb-locked cavity ring-down saturation spectroscopy. Lamb dips of 6 water lines with saturation power in the range of 70–130 kW/cm2 were observed and the line positions were determined with an accuracy of 25 kHz, corresponding to a fractional uncertainty of 6.6 × 10−11. The present work demonstrates the capability to considerably improve the accuracy of the water line positions in the infrared.

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