Abstract

This work presents accurate ab initio determination of the hyperfine splitting for the ground state and a few low-lying excited states of 113 Cd + ; important candidate for the frequency standard in the microwave region, using coupled-cluster theory (CC) in the relativistic framework. The hyperfine energy splittings, calculated first time in literature, are in good agreement with the recent experimental results. We have also carried out the lifetimes of the 5p 2 P1/2 and 5p 2 P3/2 states, which are in good agreement with the available experimental results. The role of different electron correlation effects in the determination of these quantities are discussed and their contributions are presente in the CC terms.

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