Abstract
Gap plasmonics deals with the properties of surface plasmons in the narrow region between two metallic nanoparticles forming the gap. For sub-nanometer gap distances electrons can tunnel between the nanoparticles leading to the emergence of novel charge transfer plasmons. These are conveniently described within the quantum corrected model by introducing an artificial material with a tunnel conductivity inside the gap region. Here we develop a methodology for computing such tunnel conductivities within the first-principles framework of density functional theory, and apply our approach to a jellium model representative for sodium. We show that the frequency dependence of the tunnel conductivity at infrared and optical frequencies can be significantly more complicated than previously thought.
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