Abstract
The hyperfine-structure constant A of the S, P, and D states in Cs atom with the principal quantum number are calculated using the Dirac–Fock approximation, the low-order many-body perturbation theory, and relativistic coupled-cluster method in single and double approximations with and without the inclusion of nonlinear terms. The importance of electron correlation effects, especially the nonlinear corrections of the cluster operators, is demonstrated by comparing the results of various approximations with available experimental values. Moreover, the correlation trends for individual electron correlation effects involving direct, core-polarization, and pair-correlation ones in members of Rydberg series are also investigated in the framework of the coupled-cluster theory. Some interesting features are observed.
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