Abstract
Abstract A new zinc(II)-based coordination polymer {[Zn(5-fip)(tdbpy)]·(DMF)} n (1) {5-H2fip=5-fluoroisophthalic acid, tdbpy=4,4′-(2,4,8,10-tetraoxaspiro[5.5]undecane-3,9-diyl)bispyridine, DMF=dimethylformamide} has been solvothermally synthesized and structurally characterized. Single-crystal X-ray diffraction revealed that complex 1 shows a unique two-dimensional network architecture containing single-stranded [Zn(5-fip)] n and double-stranded helical [Zn(tdbpy)] n chains. The thermal and luminescence properties of complex 1 have also been studied.
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