Abstract

The coordination polymer, namely, [Cd (L)2(phen)]n (1) (HL=2,4-dinitro-benzoic acid, phen=1,10-phenanthroline) has been hydrothermally synthesized. Compound 1 was structurally characterized by IR spectra, thermogravimetric analysis and single-crystal X-ray diffractions. The carboxylate groups of L- adopt the bridging monodentate and bidentate modes to link two Cd2+ ions, resulting in a 1-D zigzag chain structure. The solid state photoluminescent property of 1 has been investigated at room temperature.

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