Abstract
AbstractAn esterification of the C−H bond of aldehydes promoted by oxidovanadium(IV) sulfate, VIVOSO4, is reported. The process is mediated by visible‐light, is carried out at room temperature, in absence of additives and using H2O2 as a benign oxidant. VOSO4 is a commercially available, earth‐abundant metal (EAMs) salt, that does not require to be prepared. This report opens intriguing perspectives for the extended application of vanadium salts toward halogenation processes as well as for C−H activations and gives a contribution in the field of earth‐abundant metals based‐catalysis.magnified image
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