Abstract

We conducted an experimental study to unravel the oxidation of tricyclo[5.2.1.02,6]decane (JP-10) utilizing a high-temperature flow tube reactor over a temperature range of 900 K to 1031 K and the pressure of 600 Torr with the residence times of 120 ± 20 ms. The products were identified in-situ in a supersonic molecular beam via single photon vacuum ultraviolet (VUV) photoionization coupled with mass spectroscopic detection in a reflectron time-of-flight mass spectrometer (Re-TOF). 62 species – among them 25 oxygenated molecules – were identified with the oxygenated species formed via oxidation of the hydrocarbon fragments formed in the decomposition of JP-10.

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