A Uranium(VI)-Oxo-Imido Dimer Complex Derived from a Sterically Demanding Triamidoamine.

Abstract

The reaction of [UO2(μ-Cl)4{K(18-crown-6)}2] with [{N(CH2CH2NSiPri3)3}Li3] gives [{UO(μ-NCH2CH2N[CH2CH2NSiPri3]2)}2] (1), [{(LiCl)(KCl)(18-crown-6)}2] (2), and [LiOSiPri3] (3) in a 1:2:2 ratio. The formation of the oxo-imido 1 involves the cleavage of a N-Si bond and the activation of one of the usually robust U═O bonds of uranyl(VI), resulting in the formation of uranium(VI)-imido and siloxide linkages. Notably, the uranium oxidation state remains unchanged at +6 in the starting material and product. Structural characterization suggests the dominance of a core RN═U═O group, and the dimeric formulation of 1 is supported by bridging imido linkages in a highly asymmetric U2N2 ring. Density functional theory analyses find a σ > π orbital energy ordering for the U═N and U═O bonds in 1, which is uranyl-like in nature. Complexes 1-3 were characterized variously by single crystal X-ray diffraction, multinuclear NMR, IR, Raman, and optical spectroscopies; cyclic voltammetry; and density functional theory.