A unique suit of Wuchiapingian marine red beds in central China representing a specific paleogeography and paleoclimate association

Abstract

Marine red beds (MRBs) as a special geological phenomenon have been considered relevant to specific palaeogeographic or paleoclimatic conditions. The Wuchiapingian Yundoutan Formation in Xikou, Shaanxi, Central China is characterized by a huge thick succession of red limestones, which is a unique deposition among marine strata of China during the Wuchiapingian. The lithology, mineralogy, and geochemistry features of the Yundoutan Formation MRBs were analyzed by using techniques of field measurement, polarized optical microscope, field emission scanning electron microscope (FESEM), diffuse absorbance spectroscopy (DAS), X-ray diffraction (XRD), and geochemical analysis, which were used to discuss their origin and palaeogeographic and paleoclimatic responses. The results show that the stain mineral for the MRBs is mainly weakly-crystalline hematite which can not be observed in the FESEM but was detected from the DAS first derivative spectra with featured peaks around 570 nm. The similar trend of Fe with refractory elements and the strong positive correlation between Fe and Al suggest Fe is mainly a terrestrial source. Limestones of the Yundoutan Formation contain different colors including red, light gray, and dark gray. Red limestones have comparable contents of Fe with dark gray limestones, which are larger than that of light gray limestones, but they are depleted in redox-sensitive elements (Cr, Ni, Cu, Zn, Mo, U) and riched in Fe(III) compared with dark gray limestones. Those indicate that the formation of red limestones needs both enough terrestrial Fe and strong oxic conditions. A mechanism proposed for the formation of red limestones was that Fe was transported from the highlands, which were then deposited under a strong oxic environment and transformed into hematite. We suggest the Wuchiapingian MRBs formed in Central China represent a unique paleogeography and palaeoclimate association. During that time, the study area attached to the northern margin of the United North China-Qinling Block received terrestrial materials from its northward highlands, which provided Fe under a warm climate. Meanwhile, the study area located between the South and North China blocks was on the narrow seaway connecting the Palaeotethys and Panthalassa, which produced relatively fast exchanging rates of seawater and thus a high content of oxygen that can easily transform terrestrial-sourced Fe into hematite. The gradual transition among color-different limestones may be driven by the changes in rainfall that influenced river transportation on terrestrial materials or sea-level changes that influenced the redox state of the water-sediment interface.