A unified wall slip model

Abstract

A unified slip model is developed, which predicts wall slip by either a disentanglement mechanism or by debonding mechanism, depending upon the adhesive energy of the wall-polymer pair. The model is based on the transient network theory, in which the activation processes of adsorption and desorption are considered to occur at the wall in parallel to the stretching of the adsorbed chains. It is shown that the stick–slip transition occurs due to the local non-monotonic flow behavior near the wall irrespective of the mechanism of slip. The model predictions of the critical wall shear stress are in good agreement with experimentally observed values of the critical stress for various adhesive energies of wall polymer pair. Another important prediction of the model is that the temperature dependence of the critical wall shear stress for debonding is different than that of disentanglement mechanism under certain experimental conditions. This may be useful for discerning the correct mechanism of slip. The unified model encompasses different systems (viz. entangled solutions and melts) and diverse mechanisms (viz. disentanglement and debonding) in a common mathematical framework.