Abstract
AbstractA unified strategy for the synthesis of natural products containing δ‐hydroxy‐γ‐lactones as the main core is reported. This strategy is based on a photocatalyzed radical ionic sequence for the preparation of γ‐lactones. Depending on the necessities of the synthetic targets, the reaction conditions can be adjusted to access a diastereoisomeric mixture or a single diasteroisomer of the lactones. Also, δ‐lactones can be prepared by this method. The utility of this procedure was demonstrated by the total synthesis of five natural products.
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