Abstract
A competent, simplistic, and unified synthetic approach has been outlined for enantiomerically pure 3-deoxy-neo-inositol and conduritol E starting from d-ribose via a common chiral cyclohexenol derivative. The focal attributes of the synthetic route include stereoselective Grignard reaction, Wittig olefination, ring closing metathesis (RCM), and cis dihydroxylation.
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