Abstract
Abstract A twisted and partially overlapping porphyrin dimer bridged by a 1,1′-spirobiindane spacer was synthesized. Its biszinc complex and bismagnesium complex showed a split Soret band, indicating the exciton interaction of the two porphyrin ring. Bismagnesium complex underwent reversible one-electron oxidation 40 mV more easily than the corresponding monomeric porphyrin.
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