Abstract

We performed scanning tunnelling spectroscopy oninsulating colloidal CdSe quantum dots attached to gold with arigid self-assembled monolayer. By varying the tip-dot distancewe change the relative rate of tunnelling into versus tunnellingout of the dot over a wide range. If the tip is retracted relatively farfrom the dot, tunnelling in is much slower than tunnellingout of the dot; electrons tunnel one at a time through thedot. The resonances in the conductance spectrum correspond tothe single-particle energy levels of the CdSe quantum dot. Whenthe tip is brought closer to the dot, tunnelling in can becomeas fast as tunnelling out of the dot. Up to three electrons can be present in the particle; the electron-electron Coulombinteractions lead to a more complex conductance spectrum.

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