Abstract
Neue Brücken: Ein dreifach verbrückender Oxoborylligand entstand bei der Umsetzung des μ3-Borylenkomplexes [{Cp*Ru(μ-H)}3(μ3-PhCCH)(μ3-BH)] (Cp*=η5-C5Me5) mit H2O (siehe Schema). Der Mehrfachbindungscharakter der B-O-Bindung wurde durch Röntgenkristallographie, Spektroskopie und DFT-Rechnungen aufgeklärt. Die Protonierung des μ3-BO-Komplexes zu einem kationischen μ3-Hydroxyborylenkomplex bestätigt die stark polarisierte Natur der B+-O−-Bindung. As a service to our authors and readers, this journal provides supporting information supplied by the authors. Such materials are peer reviewed and may be re-organized for online delivery, but are not copy-edited or typeset. Technical support issues arising from supporting information (other than missing files) should be addressed to the authors. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.
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