Abstract
The title compound, tris(diethyl dithiophosphato)-1κ 2 S,S';2κ 2 S,S'; 3κ 2 S,S'-μ-o-nitrobenzoato-2κO:3κO'-pyridine-1κN-μ 3 -thio-tri-μ-thio-1:2κ 2 S,1:5κ 2 S,2:3κ 2 S-triangulo-trimolybdenum(3 Mo-Mo), [Mo 3 S 4 (C 7 H 4 N(C 4 H 10 PS 2 ) 3 (C 5 H 5 N)], was synthesized in a mixed solvent of acetonitrile and ethanol by a ligand substitution reaction in which o-nitrobenzoic acid replaces the bridging diethyl dithiophosphate (DTP) ligand. The average Mo-Mo bond distance is 2.731 (2) A. The substitution of o-nitrobenzoate for DTP shortens the Mo-Mo bond that it bridges to 2.693 (1) A.
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