Abstract
A study of the transferability of Urey-Bradley potential constants has been carried out with eighteen halomethanes: CX 4, CX 3Y, CX 2Y 2 and CX 2YZ, where X, Y and Z are the appropriate halogens. By using 38 force constants, good agreement between the 121 observed and calculated frequencies has been obtained in these molecules. The results lead to the reassignment of several fundamentals in CF 2I 2 and CF 2Cl 2, and confirmation of assignments in CX 2YZ: CF 2ClBr, CFCl 2Br and CFClBr 2; CX 2Y 2: CF 2Br 2 and CCl 2Br 2; CX 3Y: CF 3Cl, CF 3Br, CF 3I, CCl 3F, CCl 3Br, CBr 3F and CBr 3Cl; CX 4: CF 4, CCl 4, CBr 4 and CI 4.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
