Abstract
The adiabatic temperature change of the star-shaped {CoGd} magnetocaloric ring is enhanced via topological control over the assembly process, by using a pre-formed {CoII(H6L)} building block that undergoes oxidation to CoIII, successfully separating the GdIII ions.
Highlights
Marıa Jose Heras Ojea,a Giulia Lorusso, b Gavin A
The adiabatic temperature change of the star-shaped {CoI3IIGdI3II} magnetocaloric ring is enhanced via topological control over the assembly process, by using a pre-formed {CoII(H6L)} building block that undergoes oxidation to CoIII, successfully separating the GdIII ions
A large magnetocaloric effect (MCE) at low temperatures is favoured by a negligible magnetic anisotropy.1b,2 several molecule-based refrigerants are complexes of isotropic Gd(III) ions.[3]
Summary
Marıa Jose Heras Ojea,a Giulia Lorusso, b Gavin A.
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