Abstract

The coarsening of the two-phase, bi-continuous microstructure via surface diffusion is simulated using a three-dimensional Monte Carlo (MC) model. The coarsening exponent obtained from simulations initially decreases and then saturates at ~4 as the temperature increases. Kinetic analysis on nanoporous gold (np-Au) samples, annealed at 450 and 600 °C, confirms the prediction of the model. The coarsening probability ratio of np-Au between two annealing temperatures, calculated from the reported activation energy for coarsening of np-Au, is comparable to that of the model, signifying that the simulation successfully mimics the kinetic evolution of the thermally coarsened np-Au via surface diffusion.

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