Abstract
AbstractA three‐dimensional (3D) homochiral metal‐organic coordination polymer with a 6‐connected 412.63 topology was synthesized hydrothermally, Cd4(D‐cam)4(bbbm)2 (1) [D‐H2cam = D‐(+)‐camphoric acid and bbbm = 1,1‐(1,4‐butanediyl)bis‐1H‐benzimidazole], which represents the first example of metal‐camphorate coordination polymers constructed from two types of dinuclear cadmium clusters [Cd2(O2C–)4] and a flexible bis(benzimidazole)‐based ligand. The thermal and photoluminescent properties of 1 were investigated.
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