Abstract
The thermodynamic properties of the solid solutions formed by palladium and by platinum with iron, were investigated between 700 and 1000°C, using oxygen concentration cells with ThO 2-YO 1.5 and ZrO 2-CaO solid electrolytes. The results are given for activities, entropies and heats of mixing and are compared with recent literature data. The solid system palladium-platinum has also been shown to conform fairly closely to Raoult's law. The results for this system which were obtained by the use of the Knudsen technique are reported briefly.
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