Abstract

A novel thermodynamic approach to the quantification of the “degree of sustainability” is proposed and discussed. The method includes a rigorous -and innovative- conversion procedure of the so-called externalities that leads to their expression in terms of the exergy of their equivalent primary resources consumption. Such a thermodynamic approach suggests a detailed re-evaluation of the concept of sustainability because it is well-known that the Second Law strictly negates the possibility for any open and evolving system to maintain itself in a “sustainable” state without availing itself of a continuous supply of low-entropy (i.e., high specific exergy) input. If a human society is modeled as an open system, its capacity to “grow sustainably” depends not only on how it uses non-renewable resources, but also on the rate at which it exploits the renewable ones. The necessary inclusion of different forms of energy- and material flows in such an analysis constitutes per se an argument in favor of a resource-based exergy metrics. While it is true that the thermodynamically oriented approach proposed here neglects all of the non-thermodynamic attributes of a “sustainable system” (in the Bruntland sense), it is also clear that it constitutes a rigorous basis on which different physically possible scenarios can be rigorously evaluated. Non-thermodynamic indicators can be still used at a “second level analysis” and maintain their usefulness to indicate which one of the “thermodynamically least unsustainable” scenarios is most convenient from an ethical or socio-economic perspective for the considered community or for the society as a whole. The proposed indicator is known as “Exergy Footprint,” and the advantages of its systematic application to the identification of “sustainable growth paths” is discussed in the Conclusions.

Highlights

  • After a debate that lasted for several decades, environmental considerations have been accepted as an essential -and necessary- part of the assessment of energy conversion systems

  • This paper proposes a method to construct thermodynamically correct Environmental Indicators to rigorously address the problem of “sustainability.” Approaching the problem under this point of view, it becomes immediately clear that if the problem is tackled starting from fundamental principles a thermodynamic redefinition of the very concept of sustainability is necessary

  • A closed system is never sustainable, and an open one may be sustainable or not depending on whether the exergy input rate is higher than the sum of the exergy destruction and accumulation rates within the system, augmented by the exergy expenditure required by the environment to buffer the effect of the effluents

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Summary

A Thermodynamic Measure of Sustainability

The method includes a rigorous -and innovative- conversion procedure of the so-called externalities that leads to their expression in terms of the exergy of their equivalent primary resources consumption. Such a thermodynamic approach suggests a detailed re-evaluation of the concept of sustainability because it is well-known that the Second Law strictly negates the possibility for any open and evolving system to maintain itself in a “sustainable” state without availing itself of a continuous supply of low-entropy (i.e., high specific exergy) input.

INTRODUCTION
A BRIEF CRITICAL ANALYSIS OF THE SUSTAINABILITY CONCEPT
CONCLUSIONS
DATA AVAILABILITY STATEMENT
Indicators and methods
Full Text
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