Abstract
The thermodynamics of four new liquid crystals were investigated in order to understand their selectivity as stationary phases in gas chromatography. In this case study, liquid crystals with a benzoyloxy azobenzene mesogenic core substituted with heptyloxy (C7) and/or dioxyethylene ether (DOE) groups, were used. The chromatographic separations of linalool and citronellal, and of xylene, tetraethylbenzene and cresol isomers, which were achieved with the liquid crystal stationary phases, have been related to the dissolution thermodynamics of the solutes. The results gave us an insight into the mechanism of the molecular recognition involved in the separation processes.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.