A Thermodynamic Approach to a Density Model for Oxide Melts

Abstract

In an attempt to estimate the densities of complex slags, a model based on the thermodynamics of slags developed earlier by the present authors is extended to ternary and multi‐component systems in the present work. The molar volumes of ternary and higher order systems were derived from the relative integral molar enthalpies of mixing of the corresponding slags. The higher order of slag systems has been predicted by using the parameters from the related binary sub‐systems, which have been evaluated earlier. Comparisons of calculated results with experimental data on molar volumes available in literature show a satisfying agreement for a number of systems, within the limits of experimental uncertainties. The model presents a promising method to compute the molar volume of slag systems where no experimental data is available using the abundance of thermodynamic data available. The model would also enable the generation of density data for slags containing Al2O3, CaO, FeO, MgO, MnO, and SiO2 compatible with the corresponding thermodynamic data.