Abstract
In engineering applications, the phenomenon of cracking is often accompanied by a coupled multiphysics effect. Peridynamics (PD) is an effective approach for solving cracking problems, but currently, no general PD model accounts for the coupling of multiple physical fields. In this work, we develop a PD model of coupled deformation, heat conduction, species diffusion, and chemical reactions. First, we establish the equations for mass, linear momentum, and energy. Then we establish fully coupled constitutive laws that interpret the interactions between the various fields and formulate evolution equations that govern the flux of species and heat. These laws and equations are developed based on the inequality of energy dissipation and the principles of chemical kinetics. Species diffusion and chemical reactions are treated as separate processes to study their effects on the Helmholtz free energy density of solids and the subsequent formation and propagation of cracks. In addition, certain coupling coefficients are calibrated by equating the corresponding physical quantities in the PD model with those in continuum mechanics. Four specific cases are simulated to validate the model, including redistribution of vacancies in ceramics, hydrogen traps, and embrittlement in metals.
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