Abstract
A pcu network based on the dinuclear Ni(II) units, [Ni2(hfipbb)2(1,3-bix)2]n (1) (H2hfipbb=4,4′- (Hexafluoroisopropylidene)bis(benzoic Acid); 1,3-bix=1,3-bis(imidazol-1-ylmethyl)benzene), has been hydrothermally synthesized and structurally characterized. Interestingly, the two Ni(II) cations are bridged by two carboxylate groups in the rarely-seen syn-anti mode. The magnetic data reveal the dominant ferromagnetic interactions between Ni(II) ions.
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