Abstract
By a somewhat novel choice for an interaction representation it has been demonstrated outside a Wigner—Weisskopf ansatz that in two physically well defined situations the spectrum of light scattered by a molecule has the same form as that calculated using a one-photon wavepacket. By characterizing the exciting light using well known concepts from quantum optics we are able to describe the scattered radiation in terms of quantities which are measurable properties of real light sources and molecules.
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