Abstract

Expressions are obtained for the intensity and the quantum yield of the sensitized luminescence of the chromophore that plays the role of a reaction center in the simplest model trichromophore molecular [light‐collecting] antenna which is so constructed and so oriented in space that the irradiation photons coherently excite its other two chromophores‐pigments. The quantum electrodynamics formalism which takes into account the radiative dissipative interaction between the pigments and the reaction center of the antenna was used. The comparative analysis of the obtained expressions with the corresponding expressions for the luminescence of a bichromophore molecular system, differing from the trichromophore antenna by the absence of one of the pigments, has shown that the collective dissipative interaction of the pigments with the reaction center of the antenna can be considered as a highly efficient mechanism of [light collection] in molecular antennas.

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