Year-end Sale % OFF 
Abstract
Many data, collected from the literature, support the postulation of two general rules which describe the static and dynamic results of having in a molecule or generating in an intermediate adjacent electron pairs and/or polar bonds. In disagreement with current chemical intuition, structures which contain the maximum number of gauche-interactions between lone electron pairs or polar bonds represent energy minima and, frequently, the lowest minima. The stereochemical implications of the phenomenon are discussed, along with possible physical explanations. It is suggested that partitioning of the total energy of the system into attractive-dominant and repulsive-dominant interactions provides the most helpful framework for the construction of a physical picture of the phenomenon. The total energy and its components can be obtained by ab initio molecular quantum mechanical calculations.
Published Version
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
