Abstract

An equation which involves the triplet distribution function and the three-particle direct correlation function is obtained. This equation was derived using an analogue of the Ornstein–Zernike equation. The new equation is used to develop a variational method for obtaining the triplet distribution function of uniform one-component atomic fluids from the pair distribution function. The variational method may be used with the first and second equations in the YBG hierarchy to obtain pair and triplet distribution functions. It should be easy to generalize the results to the n-particle distribution function.

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