Abstract

A novel method for the N−N bond cleavage of trimethylsilyl diazomethane is reported for the synthesis of terminal nitride complexes. The lithium salt of trimethylsilyl diazomethane was used to generate a rare terminal nitrilimine transition metal complex with partially occupied d‐orbitals. This iron complex 2 was characterized by CHN combustion analysis, 1H and 13C NMR spectroscopic analysis, single‐crystal X‐ray crystallography, SQUID magnetometry, 57Fe Mössbauer spectroscopy, and computational analysis. The combined results suggest a high‐spin d 6 (S=2) electronic configuration and an allenic structure of the nitrilimine ligand. Reduction of 2 results in release of the nitrilimine ligand and formation of the iron(I) complex 3, which was characterized by CHN combustion analysis, 1H NMR spectroscopic analysis, and single‐crystal X‐ray crystallography. Treatment of 2 with fluoride salts quantitatively yields the diamagnetic FeIV nitride complex 4, with concomitant formation of cyanide and trimethylsilyl fluoride through N−N bond cleavage.

Highlights

  • A novel method for the NÀN bond cleavage of trimethylsilyl diazomethane is reported for the synthesis of terminal nitride complexes

  • The lithium salt of trimethylsilyl diazomethane was used to generate a rare terminal nitrilimine transition metal complex with partially occupied d-orbitals. This iron complex 2 was characterized by CHN combustion analysis, 1H and 13C NMR spectroscopic analysis, single-crystal X-ray crystallography, SQUID magnetometry, 57Fe Mçssbauer spectroscopy, and computational analysis

  • Reduction of 2 results in release of the nitrilimine ligand and formation of the iron(I) complex 3, which was characterized by CHN combustion analysis, 1H NMR spectroscopic analysis, and single-crystal X-ray crystallography

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Summary

Introduction

Abstract: A novel method for the NÀN bond cleavage of trimethylsilyl diazomethane is reported for the synthesis of terminal nitride complexes. The lithium salt of trimethylsilyl diazomethane was used to generate a rare terminal nitrilimine transition metal complex with partially occupied d-orbitals.

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