Abstract

Summary of main observation and conclusionThe influence of magnetic interactions to the magnetization dynamics was well experimentally studied in a 3d‐4f single‐molecule magnet (SMM) [TbIII2FeIII3(μ5‐O)L2(NO3)4Cl] (1, H4L = N,N,N’,N’‐tetrakis(2‐hydroxyethyl)ethylene diamine) and its diamagnetic‐ ion‐diluted samples. Significant ferromagnetic coupling between TbIII and FeIII ions and SMM behavior of 1 were observable, which proved clearly that the magnetic interaction between 3d‐4f spin carriers has also an excessive impact on fine‐tuning the magnetization dynamic behaviors of 3d‐4f complexes.

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