Abstract
A novel tandem reaction, including nucleophilic addition, defluorination and destannylation reactions, has been found and its application to the stereospecific synthesis of trifluoromethylated alkyl- and aryl vinyl etherswith exclusive formation of E-isomers in 73-96% yields is reported. An Ad N -E mechanism for the tandem reaction leading to alkyl- and aryl vinyl ethers is proposed.
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