Abstract
Since the freezing point of a solution is by definition the temperature at which the solution and crystals of pure solvent are in equilibrium, it is necessary in any careful cryoscopic work to correct the observed temperature at equilibrium, A' as read from the thermometer, for the concentration of the solution by the separation of the solid phase of the solvent to obtain the true freezing-point lowering of the original solution. Jones 1 many years ago pointed out that the concentration of the solution by the separation of crystals of solvent may be expressed by
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