Abstract
Tricycle 6 , containing the CD ring of taxol, is constructed from ( S)-(+)-carvone in 21 steps involving a Diels–Alder reaction with isoprene, a Baeyer–Villiger oxidation, an Oppenaurer oxidation and Meerwein–Ponndorf–Verley reduction, a stereospecific Grignard addition, and an intramolecular S N2 reaction as the key steps.
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