Abstract

Electrochemical removal of NO and NO 2 by using Ag(I)/Ag(II) redox mediator system in nitric acid medium by two-stage scrubbing process was investigated. Experiments were carried out for the complete removal of NO and NO 2 from the stimulated flue gas at room temperature and atmospheric pressure. The process parameters like current density, Ag(I) concentration, HNO 3 concentration, initial concentration of NO, Ag(I) concentration and temperature were studied and optimized. A removal efficiency of >99% was achieved using this sustainable redox process. Ag(II)/Ag(I) can be regenerated and reused for the scrubbing of waste gases continuously and there is no other gases emission during scrubbing.

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