Abstract
A flexible open framework, {[Co2(L)Cl(DMF)2(H2O)]·Sx}n (H3L = 4,4′,4′′-[1,3,5-benzenetriyltris(carbonylimino)]-trisbenzoic acid, DMF = dimethylformamide), was constructed based on a honeycomb coordination subunit with both octahedral and tetrahedral CoII sites, showing moderate MeOH sorption and antiferromagnetic properties.
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