A supramolecular hydrogen‐bonded complex between 1,3,5‐tris(diisobutylhydroxysilyl)benzene and trans‐bis(4‐pyridyl)ethylene

Jens Beckmann,Sanna L Jänicke

doi:10.1002/aoc.1261

A supramolecular hydrogen‐bonded complex between 1,3,5‐tris(diisobutylhydroxysilyl)benzene and trans‐bis(4‐pyridyl)ethylene

Jens Beckmann, Sanna L Jänicke

https://doi.org/10.1002/aoc.1261

Copy DOI

Journal: Applied Organometallic Chemistry	Publication Date: Jun 7, 2007
Citations: 5

Affiliation: Freie Universität Berlin

#Sequential Hydrogen Bonds #Hydrogen Bridges + Show 6 more

Abstract
Full-Text
Similar Papers

Abstract

AbstractThe trisilanol 1,3,5‐(HOi‐Bu2Si)3C6H3 (7), prepared in three steps from 1,3,5‐tribromobenzene via the intermediates 1,3,5‐(Hi‐Bu2Si)3C6H3 (8) and 1,3,5‐(Cli‐Bu2Si)3C6H3 (9) forms an equimolar complex with trans‐bis(4‐pyridyl)ethylene (bpe), 7·bpe, whose structure was investigated by X‐ray crystallography. The hydrogen‐bonded network features a number of SiOH(H)Si and SiOH hydrogen bridges. Evidence was found for cooperative strengthening within the sequential hydrogen bonds. Copyright © 2007 John Wiley & Sons, Ltd.

Talk to us

Join us for a 30 min session where you can share your feedback and ask us any queries you have

Schedule a call

Similar Papers

Paper Title

Journal

Date

Author

View more papers

More From: Applied Organometallic Chemistry

Paper Title

Journal

Date

Author

View more papers

Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.